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11.
Lanças FM Olivares IR Alves PM 《Journal of environmental science and health. Part. B》2007,42(5):491-498
In this work the development, validation and application of method using Solid Phase Microexctration (SPME) for the analyses of five pollutants (phenol, 2-nitrophenol, 2,4-dimethylphenol, 2,4-dichlorophenol and 4-chloro, 3-methyl phenol) in supplying water, using gas chromatography (GC) with flame ionization detector (FID) is described. The optimal conditions obtained for SPME were: fiber type: Poliacrylate (PA); extraction time: 40 minutes; extraction temperature: 70 degrees C; amount of salt added to sample (NaCl): 15%; desorption temperature: 8 minutes. The parameters studied in the method validation were: limit of detection (0.3 and 3.5 microg.L(- 1)); precision, measured by the variation coefficient (between 2.1 and 8.8%); calibration curve and linearity, by using the external standardization method (between 1 and 50 50 microg.L(- 1)). After the methodology development, samples of water collected in Atibaia River (S?o Paulo - Brazil) were analyzed, using the optimized methodology. Three water samples collected in the rain season showed a peak with retention time close to 4-chloro, 3 methyl phenol further analyzed by Gas Chromatography-Mass Spectrometry for the identity confirmation. In spite of the fact that none target compounds were found in the river water samples analyzed, the presence of two phenols different from those investigated (p-terc butyl phenol; butylated hydroxytoluene) were detected. These results together with the results of the limit of detection (that showed to be lower than the maximum concentration of phenols demanded by different environment control agencies), and the results of the validation, indicate the applicability of this method for the analysis of selected phenols in river water samples. 相似文献
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In the 1950s, a production plant of hexachlorocyclohexane (HCH) was established in Brazil with the main purpose of producing chemicals for vectors control. This factory was closed down in 1955 and around 300 tons of production residues were left behind in the open air. In 1995, the area was treated with lime to eliminate the HCH contamination. Soil sample gave a PCDD/F concentration of 13 900 ng I-TEQ/kg whereas samples from the neighborhood ranged from 0.19 to 2.08 ng I-TEQ/kg. PCDD/F levels in cow's milk samples varied from 4.1 to 6.5 pg I-TEQ/g of milk fat. High concentration in soil collected from the site suggests that treatment and recovery shall be made. Further dioxin monitoring is needed to better estimate the risk posed to local population through food consumption and soil usage. 相似文献
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Tavares Priscila da Silva Giarolla Angélica Chou Sin Chan Silva Adan Juliano de Paula Lyra André de Arruda 《Regional Environmental Change》2018,18(3):873-883
Regional Environmental Change - The Intergovernmental Panel on Climate Change (IPCC) projections of global mean temperature rises are worrisome for coffee crop due to the intolerance of the Arabica... 相似文献
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Ximenes Carolina Falcão Rodrigues Samya Mere Lima Podratz Priscila Lang Merlo Eduardo de Araújo Julia Fernandez Puñal Rodrigues Lívia Carla Melo Coitinho Juliana Barbosa Vassallo Dalton Valentim Graceli Jones Bernardes Stefanon Ivanita 《Environmental science and pollution research international》2017,24(31):24509-24520
Environmental Science and Pollution Research - Organotin compounds, such as tributyltin (TBT), are environment contaminants that induce bioaccumulation and have potential toxic effects on marine... 相似文献
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Gomes-Junior RA Moldes CA Delite FS Pompeu GB Gratão PL Mazzafera P Lea PJ Azevedo RA 《Chemosphere》2006,65(8):1330-1337
The antioxidant responses of coffee (Coffea arabica L.) cell suspension cultures to cadmium (Cd) were investigated. Cd accumulated very rapidly in the cells and this accumulation was directly correlated with an increase in applied CdCl(2) concentration in the external medium. At 0.05mM CdCl(2), growth was stimulated, but at 0.5mM CdCl(2), the growth rate was reduced. An alteration in activated oxygen metabolism was detected by visual analysis as well as by an increase in lipid peroxidation at the higher CdCl(2) concentration. Catalase (CAT; EC 1.11.1.6), glutathione reductase (GR; EC 1.6.4.2) and superoxide dismutase (SOD; EC 1.15.1.1) activity increased, particularly at the higher concentration of CdCl(2). Ascorbate peroxidase (APX; EC 1.11.1.11) activity was increased at the lower CdCl(2) concentration used, but could not be detected in cells growing in the higher CdCl(2) concentration after 24h of growth, whilst guaiacol peroxidase (GOPX; EC 1.11.1.7) did not show a clear response to Cd treatment. An analysis by non-denaturing PAGE followed by staining for enzyme activity, revealed one CAT isoenzyme, nine SOD isoenzymes and four GR isoenzymes. The SOD isoenzymes were differently affected by CdCl(2) treatment and one GR isoenzyme was shown to specifically respond to CdCl(2). The results suggest that the higher concentrations of CdCl(2) may lead to oxidative stress. The main response appears to be via the induction of SOD and CAT activities for the removal of reactive oxygen species (ROS), and by the induction of GR to ensure the availability of reduced glutathione for the synthesis of Cd-binding peptides, which may also be related to the inhibition of APX activity probably due to glutathione and ascorbate depletion. 相似文献
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Lopes Géssica de Oliveira Aragão Walessa Alana Bragança Nascimento Priscila Cunha Bittencourt Leonardo Oliveira Oliveira Ana Carolina Alves Leão Luana Ketlen Reis Alves-Júnior Sergio Melo Pinheiro João de Jesus Viana Crespo-Lopez Maria Elena Lima Rafael Rodrigues 《Environmental science and pollution research international》2021,28(9):10918-10930
Environmental Science and Pollution Research - This study aimed to investigate the effects of lead (Pb) exposure on parotid and submandibular glands through morphological aspects as well as the... 相似文献
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Lopes Priscila F. M. Pennino Maria Grazia Freire Fúlvio 《Regional Environmental Change》2018,18(1):223-234
Regional Environmental Change - Shrimps are an important and valuable fishing resource, being increasingly exploited worldwide, demanding appropriate management. However, factors such as how... 相似文献
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Honscha Laiz Coutelle Penteado Julia Oliveira de Sá Gama Valério da Silva Bonifácio Alícia Aikawa Priscila dos Santos Marina Baisch Paulo Roberto Martins Muccillo-Baisch Ana Luíza da Silva Júnior Flavio Manoel Rodrigues 《Environmental science and pollution research international》2022,29(10):14176-14184
Environmental Science and Pollution Research - Coal exploration and burning activities are among the activities with the greatest potential to cause atmospheric pollution due to the combustion... 相似文献
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Planarian neoblasts are somatic stem cells that have the potential to be used in genotoxicity assays due to their proliferative nature, sensitivity to genotoxic agents, and experimental accessibility. Two freshwater planarian species, Girardia tigrina and Girardia schubarti, were used to develop a neoblast-based micronucleus (MN) assay to assess genotoxicity. Intact or regenerating planarians were exposed to gamma-rays, methyl methanesulphonate (MMS), or cyclophosphamide (CP), and neoblast MN frequency was measured. Exposure to the clastogens had no detectable effect on the MN frequency of intact planarian neoblasts. However, for regenerating individuals, active neoblast proliferation was induced by decapitation, and gamma-ray doses as low as 0.5 Gy, and MMS and CP concentrations as low as 0.8 microM and 100 mM, respectively, induced a significant increase in MN frequency. Exposure to higher doses of gamma-rays consistently resulted in detectable increases in MN frequency. For MMS and CP, concentrations of up to 1.6 microM and 200 mM, respectively, resulted in significant increases in MN frequency, but exposures to higher concentrations led to a decrease to non-significant levels, possibly due to cytotoxic effects of MMS and CP. After completion of regeneration, the MN frequencies returned to those of non-exposed controls, indicating that the neoblast MN assay for regenerating G. tigrina or G. schubarti reflects chromosomal damage caused by acute exposure to clastogenic agents. Upon standardization, this assay may represent an interesting alternative that allows damage caused to freshwater organisms by potentially genotoxic environmental pollutants to be monitored. 相似文献